Pre-heat your oven to 390℉/180℃. Line 12 muffin holes with cupcake/muffin liners.
In a small bowl, break up the dark chocolate and melt in the microwave in 20 second intervals, stirring in between to make sure it doesn't burn. Alternatively, set up a double boiler. Do this by placing a heatproof bowl over a small pot of simmering water. Add the chocolate to the heatproof bowl and stir until melted.
In a large mixing bowl, whisk together melted butter and both sugars. With an electric/stand mixer, go for a solid 3-5minutes so it is totally combined. Add in the eggs and vanilla and whisk.
Now, add the melted chocolate slowly and combine once again.
Add the flour, cocoa powder and a pinch of salt – fold gently into the wet mixture with a rubber spatula or wooden spoon until just combined. Pour heaped tablespoons into each muffin cup. Don't be afraid to fill close to the top, they don't rise much.
Bake 20-25 minutes until looking crinkly on top and with minimal wobble. While still warm, create indents in each brownie cup. Use a tablespoon measure, the end of a wooden spoon, an egg cup or anything else that works to press down the middle. Let cool.