In a large bowl, using an electric/stand mixer (or hand whisk, just double/triple the times) combine the butter and both sugars on medium speed for several minutes, until fully combined. Add the egg and vanilla and mix again.
Add the flour, baking powder, butterscotch angel delight/pudding mixture and chopped chocolate, and fold until combined. The dough should be fairly solid at this stage (it ought to almost form a ball, albeit a very soft one!).
Cover and chill in the fridge at least 30 minutes.
Preheat the oven to 200C/180C Fan/Gas 6. Line 2-3 large baking trays. Roll into about 12 balls (use a tablespoon to scoop balls of dough). Place on lined baking sheets.
Bake 10-12 minutes, until golden and just crisping up at the edges (they continue to cook a little once removed). Let cool on a wire rack before adding the glitter if using!