Pre-heat your oven to 390℉/180℃. Line 12 muffin holes with cupcake/muffin liners.
In a small bowl, break up the dark chocolate and melt in the microwave in 20 second intervals, stirring in between to make sure it doesn't burn. Alternatively, set up a double boiler. Do this by placing a heatproof bowl over a small pot of simmering water. Add the chocolate to the heatproof bowl and stir until melted.
In a large mixing bowl, whisk together melted butter and both sugars. With an electric/stand mixer, go for a solid 3-5minutes so it is totally combined. Add in the eggs, one at a time and mixing in between.
Now, add the melted chocolate slowly and combine once again.
Add the flour and cocoa powder, fold gently into the wet mixture with a rubber spatula or wooden spoon until just combined.
Fill each cup to about 3/4 full, they don't rise much.
Bake 15-18 minutes. While warm, use something like the end of a wooden spoon or tablespoon measure to create deep indents in the centre of each brownie cup. Let cool.
Once cool, add about a teaspoon of caramel sauce to each brownie cup. Sprinkle over some chopped peanuts.