Pre-heat your oven to 180℃ Fan/370℉. Line an 8" Square Pan with greaseproof paper.
In a small bowl, break up the dark chocolate and melt in the microwave in 20 second intervals, stirring in between to make sure it doesn't burn. Alternatively, set up a double boiler. Do this by placing a heatproof bowl over a small pot of simmering water. Add the chocolate to the heatproof bowl and stir until melted.
In a large mixing bowl, or the bowl of a stand mixer, whisk together melted butter and both sugars. Then add the melted chocolate and combine. Add the eggs and vanilla and whisk until the smooth batter comes together.
Add the flour and cocoa powder. Fold gently into the wet mixture with a rubber spatula or wooden spoon until just combined. Pour into the lined tin.
Bake 25-30 minutes until the top is shiny and it's still just a little wobbly in the middle. Let cool.